[(η 5 ‐Cp) 2 Sn(μ‐η 5 ‐Cp)Na · PMDETA], a Compound with a Trigonal‐Planar “Paddle Wheel” Triorganostannate Ion | Zendy

Davidson Matthew G. | Zendy; Stalke Dietmar | Zendy; Wright Dominic S. | Zendy

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[(η 5 ‐Cp) 2 Sn(μ‐η 5 ‐Cp)Na · PMDETA], a Compound with a Trigonal‐Planar “Paddle Wheel” Triorganostannate Ion

Author(s) -

Davidson Matthew G.,

Stalke Dietmar,

Wright Dominic S.

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199212261

Subject(s) - ion , crystallography , trigonal crystal system , chemistry , planar , atom (system on chip) , solid state , stereochemistry , crystal structure , computer graphics (images) , organic chemistry , computer science , embedded system

An organotin( II ) anion with three η 5 ‐Cp ligands and a Sn atom in a trigonal‐planar environment are found in the title compound 1 (see diagram), obtained from the reaction of CpNa, [Cp 2 Sn], and PMDETA (mol ratio 1:1:1). This [Cp 3 Sn] − ion is linked to the Na + ion by a μ‐η 5 ‐Cp bridge. Compound 1 is a polymeric array in the solid state due to intermolecular C(H) … Na interactions. PMDETA = (Me 2 NCH 2 CH 2 ) 2 NMe.

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