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Indirect 113 Cd, 14 N Spin‐Spin Coupling Constants as a Structural Probe of Solid Cadmium Thiocyanate Complexes
Author(s) -
Eichele Klaus,
Wasylishen Roderick E.
Publication year - 1992
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199212221
Subject(s) - multiplet , thiocyanate , cadmium , spin (aerodynamics) , chemistry , coupling constant , measure (data warehouse) , coupling (piping) , crystallography , metal , inorganic chemistry , physics , spectral line , materials science , quantum mechanics , thermodynamics , database , computer science , metallurgy , organic chemistry
The number of the N ‐bound thiocyanato ligands is only a part of the wealth of information that can be extracted from the 113 CdNMR spectrum of solid 1 . For instance, the splitting in the well‐resolved multiplet signals (see right), which results from direct and indirect 113 Cd 14 N coupling appears to be a measure of the CdN distances. In contrast, NMR studies of metal thiocyanates in solution are rather uninforma‐tive.