The Electrochemical Oxidation of [Co  II  (salen)] in Solvent Mixtures—An Example of a Ladder Scheme with Coupled Electron‐Transfer and Solvent‐Exchange Reactions | Zendy

Eichhorn Emerich | Zendy; Rieker Anton | Zendy; Speiser Bernd | Zendy

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The Electrochemical Oxidation of [Co II (salen)] in Solvent Mixtures—An Example of a Ladder Scheme with Coupled Electron‐Transfer and Solvent‐Exchange Reactions

Author(s) -

Eichhorn Emerich,

Rieker Anton,

Speiser Bernd

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199212151

Subject(s) - electrochemistry , electron transfer , redox , chemistry , solvent , catalysis , electron exchange , electrode , chemical reaction , inorganic chemistry , photochemistry , organic chemistry , ion

Every electron‐transfer reaction of a complex process on the electrode , in which individual electron‐transfer and chemical reaction steps are coupled in such a way that a cyclic sequence results, was observed separately for the first time in the electrochemical investigation of the Co II complex 1 . This is crucial for the detailed description of the catalytic activity of 1 , because, as shown here, the redox reactions are strongly dependent on solvent.

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