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Bis(trisyl)oxadiborirane
Author(s) -
Paetzold Peter,
GéretBaumgarten Laurence,
Boese Roland
Publication year - 1992
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199210401
Subject(s) - diborane , chemistry , ab initio , yield (engineering) , molecule , atom (system on chip) , crystallography , chain (unit) , computational chemistry , boron , physics , thermodynamics , organic chemistry , quantum mechanics , computer science , embedded system
The oxadiborirane 1 is unexpectedly unreactive . In this molecule the almost linear CBBC chain and very short BB distance agree with predictions based on ab initio calculations that suggest that 1 is a diborane(2) RBBR with a side‐on coordinated O atom. Compound 1 is formed according to Equation (a) in 54 % overall yield. M = Na/K alloy.