Bis(trisyl)oxadiborirane | Zendy

Paetzold Peter | Zendy; GéretBaumgarten Laurence | Zendy; Boese Roland | Zendy

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Bis(trisyl)oxadiborirane

Author(s) -

Paetzold Peter,

GéretBaumgarten Laurence,

Boese Roland

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199210401

Subject(s) - diborane , chemistry , ab initio , yield (engineering) , molecule , atom (system on chip) , crystallography , chain (unit) , computational chemistry , boron , physics , thermodynamics , organic chemistry , quantum mechanics , computer science , embedded system

The oxadiborirane 1 is unexpectedly unreactive . In this molecule the almost linear CBBC chain and very short BB distance agree with predictions based on ab initio calculations that suggest that 1 is a diborane(2) RBBR with a side‐on coordinated O atom. Compound 1 is formed according to Equation (a) in 54 % overall yield. M = Na/K alloy.

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