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A One‐Pot Synthesis of Ketones and Aldehydes from Carbon Dioxide and Organolithium Compounds
Author(s) -
Zadel Guido,
Breitmaier Eberhard
Publication year - 1992
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199210351
Subject(s) - organolithium compounds , carbon dioxide , chemistry , organic chemistry , substitution (logic) , ion , computer science , deprotonation , programming language
Ketones and aldehydes with almost any substitution pattern can be prepared from carbon dioxide according to Reaction (a). By varying the reaction conditions (short reaction time, excess of the alkyllithium compound) certain tertiary alcohols may also be obtained.