Stepwise Synthesis of Binuclear Photoactive Complexes with a Bridging 3, 4‐Dihy droxyphenylterpyridine Ligand | Zendy

Howard Christine A. | Zendy; Ward Michael D. | Zendy

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Stepwise Synthesis of Binuclear Photoactive Complexes with a Bridging 3, 4‐Dihy droxyphenylterpyridine Ligand

Author(s) -

Howard Christine A.,

Ward Michael D.

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199210281

Subject(s) - dication , bridging (networking) , chemistry , bridging ligand , ligand (biochemistry) , stereochemistry , photochemistry , crystallography , molecule , crystal structure , receptor , organic chemistry , computer science , biochemistry , computer network

Heteropolynuclear compounds with photoactive groups can be synthesized in a controlled, stepwise manner, if first the N atoms of the 3,4‐dimethoxyphenylterpyridine ligands are coordinated to a Ru II complex fragment, then the second binding positions (OR groups) are unmasked and coordinated to a Pd complex fragment. Strong electronic interactions exist between the two parts of the complex in dication 1 , which result in interesting photochemical properties.

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