The Reaction of [Cp       2    +    Nb 2 (B 2 H 6 ) 2 ] (Cp +  = η/‐EtMe 4 C 5 ) with Sulfur: Stabilization of the Tetrathioborato Ligand in Novel Sulfido Niobium Clusters | Zendy

Brunner Henri | Zendy; Gehart Günther | Zendy; Wachter Joachim | Zendy; Nuber Bernd | Zendy; Ziegler Manfred L. | Zendy

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The Reaction of [Cp 2 + Nb 2 (B 2 H 6 ) 2 ] (Cp + = η/‐EtMe 4 C 5 ) with Sulfur: Stabilization of the Tetrathioborato Ligand in Novel Sulfido Niobium Clusters

Author(s) -

Brunner Henri,

Gehart Günther,

Wachter Joachim,

Nuber Bernd,

Ziegler Manfred L.

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199210211

Subject(s) - equilateral triangle , cluster (spacecraft) , sulfur , chemistry , tetrahedron , crystallography , group 2 organometallic chemistry , molecule , geometry , mathematics , organic chemistry , computer science , programming language

An equilateral Nb 3 triangle the edges of which are spanned by a BS 4 tetrahedron and bridged by sulfido ligands on the “underside” is found in cluster 1 . The synthesis of this cluster with an unusual electron configuration shows that tetrathioborates can serve as ligands in organometallic chemistry. C p += η 5 ‐EtMe 4 C 5 .

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