Molecular Recognition of Primary Amines by Three‐Point Binding with Boron‐Containing Host Molecules | Zendy

Reetz Manfred T. | Zendy; Niemeyer Christof M. | Zendy; Hermes Marcus | Zendy; Goddard Richard | Zendy

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Molecular Recognition of Primary Amines by Three‐Point Binding with Boron‐Containing Host Molecules

Author(s) -

Reetz Manfred T.,

Niemeyer Christof M.,

Hermes Marcus,

Goddard Richard

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199210171

Subject(s) - amine gas treating , molecule , primary (astronomy) , boron , molecular recognition , hydrogen bond , chemistry , ether , crown ether , crystallography , organic chemistry , physics , ion , astronomy

The reversible formation of a dative bond between the boron center (M) of the host and the N atom of the primary amine, with simultaneous formation of hydrogen bonds between the amine H atoms and two oxygen atoms (D) of the crown ether host presents a new concept in molecular recognition (depicted schematically right). The control of the degree and direction of the molecular recognition by variation of the groups R on the amine is unprecedented.

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