Multidentate Macrocyclic Lewis Acids: Release of “[12] Mercuracarborand‐4” from Its Iodide Complex and the Structure of Its Tetra(tetrahydrofuran) Dihydrate Complex | Zendy

Yang Xiaoguang | Zendy; Johnson Stephen E. | Zendy; Khan Saeed I. | Zendy; Hawthorne M. Frederick | Zendy

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Multidentate Macrocyclic Lewis Acids: Release of “[12] Mercuracarborand‐4” from Its Iodide Complex and the Structure of Its Tetra(tetrahydrofuran) Dihydrate Complex

Author(s) -

Yang Xiaoguang,

Johnson Stephen E.,

Khan Saeed I.,

Hawthorne M. Frederick

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199208931

Subject(s) - tetrahydrofuran , iodide , denticity , chemistry , halogen , lewis acids and bases , tetra , polymer chemistry , medicinal chemistry , organic chemistry , crystal structure , alkyl , catalysis , solvent

One or two iodide ions can be bound by the Lewis‐acidic host “[12] mercuracarborand‐4” 1 , as is shown by 199 Hg NMR spectroscopic studies. The halogen‐free macrocycle 1 is accessible from 1 . I 2 Li 2 and silver acetate, and could be structurally characterized as the tetrakis(tetrahydrofuran) complex.

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