The First Complex with a σ 2 π 4  Triple Bond between Vanadium Atoms in a Ligand Framework of Fourfold Symmetry—[V 2 {( p ‐CH 3 C 6 H 4 )NC(H)N( p ‐C 6 H 4 CH 3 )} 4 ] | Zendy

Cotton F. Albert | Zendy; Daniels Lee M. | Zendy; Murillo Carlos A. | Zendy

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The First Complex with a σ 2 π 4 Triple Bond between Vanadium Atoms in a Ligand Framework of Fourfold Symmetry—[V 2 {( p ‐CH 3 C 6 H 4 )NC(H)N( p ‐C 6 H 4 CH 3 )} 4 ]

Author(s) -

Cotton F. Albert,

Daniels Lee M.,

Murillo Carlos A.

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199207371

Subject(s) - vanadium , triple bond , intermetallic , ligand (biochemistry) , symmetry (geometry) , anisotropy , bond , crystallography , chemistry , stereochemistry , physics , inorganic chemistry , double bond , mathematics , organic chemistry , receptor , business , quantum mechanics , geometry , biochemistry , alloy , finance

The long quest for a VV triple bond has finally met with success, as shown by the synthesis of the title compound 1. A short intermetallic distance and high magnetic anisotropy indicate strong interaction between the vanadium centers. R = p ‐CH 3 C 6 H 4 .

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