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The First Reaction of S 5 N 6 ; Structure of a Complex Containing an S 2 N 3 − Ligand
Author(s) -
Kelly Paul F.,
Slawin Alexandra M. Z.,
Williams David J.,
Woollins J. Derek
Publication year - 1992
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199206161
Subject(s) - bond length , sulfur , crystallography , explosive material , ligand (biochemistry) , product (mathematics) , chemistry , ion , metal , mathematics , crystal structure , geometry , organic chemistry , biochemistry , receptor
A new pattern of SN bond lengths is found in the anion of (PPh 4 )[PdCl 2 (S 2 N 3 )] (see structure shown), the product of the reaction of explosive S 5 N 6 with (PPh 4 ) 2 [Pd 2 Cl 6 ]. The distances between sulfur and bridgehead N atoms average 1.604 Å and between sulfur and metal‐coordinated N atoms 1.486 Å; the latter bond lengths are among the shortest known in M‐S‐N rings.
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