OH Bond Activation in the Gas Phase: The Reactions of Water and Methanol with [FeCH 3 ] + | Zendy

Blum Ofer | Zendy; Stöckigt Detlef | Zendy; Schröder Detlef | Zendy; Schwarz Helmut | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

OH Bond Activation in the Gas Phase: The Reactions of Water and Methanol with [FeCH 3 ] +

Author(s) -

Blum Ofer,

Stöckigt Detlef,

Schröder Detlef,

Schwarz Helmut

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199206031

Subject(s) - chemistry , deuterium , methanol , molecule , kinetic isotope effect , atom (system on chip) , cationic polymerization , phase (matter) , crystallography , stereochemistry , medicinal chemistry , organic chemistry , atomic physics , physics , computer science , embedded system

That even cationic fragments of late transition metals can activate OH bonds in the gas phase is shown by studies of reaction (a) (RH, CH 3 ), in which a large deuterium isotope effect can be observed ( k H / /k D > 15). An oxidative addition mechanism is proposed for this transformation; the first step is the coordination of the dipolar H 2 O or CH 3 OH molecule to the [FeCH 3 ] + fragment, while the rate‐determining step is the transfer of the H atom of the ROH group to the Fe atom.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research