Bismuth Alkoxide Dimer Complexes Containing Planar Bi 2 (μ‐OR) 2  Cores: Syntheses and Structures of [{Bi[OCH(CF 3 ) 2 ] 3 (thf)} 2 ] and [{Bi(OC 6 F 5 ) 3 (C 7 H 8 )} 2 ] · 2C 7 H 8 | Zendy

Jones Carolyn M. | Zendy; Burkart Michael D. | Zendy; Whitmire Kenton H. | Zendy

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Bismuth Alkoxide Dimer Complexes Containing Planar Bi 2 (μ‐OR) 2 Cores: Syntheses and Structures of [{Bi[OCH(CF 3 ) 2 ] 3 (thf)} 2 ] and [{Bi(OC 6 F 5 ) 3 (C 7 H 8 )} 2 ] · 2C 7 H 8

Author(s) -

Jones Carolyn M.,

Burkart Michael D.,

Whitmire Kenton H.

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199204511

Subject(s) - alkoxide , dimer , lone pair , crystallography , octahedron , bismuth , monomer , chemistry , molecule , atom (system on chip) , electron pair , materials science , stereochemistry , inorganic chemistry , crystal structure , electron , physics , polymer , organic chemistry , catalysis , quantum mechanics , computer science , embedded system

A potential precursor for the production of high‐temperature superconductors , the loose dimer 1 is bound by two asymmetric alkoxide bridges (a monomeric unit is shown right). The Bi atoms in 1 are surrounded in a distorted pseudo‐octahedral fashion by one bridging and two terminal alkoxide ligands and a THF molecule. Each Bi atom also has a stereochemically active lone pair of electrons.

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