A Straightforward Synthesis of Nitrilimines; X‐Ray Crystal Structure of a Nitrilimine Stabilized by Non‐Heteroatom Substituents | Zendy

Réau Régis | Zendy; Veneziani Guilaine | Zendy; Dahan Françoise | Zendy; Bertrand Guy | Zendy

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A Straightforward Synthesis of Nitrilimines; X‐Ray Crystal Structure of a Nitrilimine Stabilized by Non‐Heteroatom Substituents

Author(s) -

Réau Régis,

Veneziani Guilaine,

Dahan Françoise,

Bertrand Guy

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199204391

Subject(s) - chemistry , heteroatom , steric effects , medicinal chemistry , diazomethane , yield (engineering) , crystal structure , crystallography , photochemistry , ring (chemistry) , stereochemistry , organic chemistry , materials science , metallurgy

Air‐stable crystals of bis(triphenylmethyl)‐substituted nitrilimine 3 are produced in 90% yield from the reaction of bis(trimethylstannyl)diazomethane 1 with triphenylmethyl chloride. The stability of 3 can only be explained by steric effects, since the electronic interaction of the Ph 3 C substituents with the CNN frame is not evident. Compound 3 reacts as a 1,3‐dipole.

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