The Triolide of ( R )‐3‐Hydroxybutyric acid—Direct Preparation from Polyhydroxybutyrate and Formation of a Crown Estercarbonyl Complex with Na Ions | Zendy

Seebach Dieter | Zendy; Müller HansMartin | Zendy; Bürger H. Michael | Zendy; Plattner Dietmar A. | Zendy

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The Triolide of ( R )‐3‐Hydroxybutyric acid—Direct Preparation from Polyhydroxybutyrate and Formation of a Crown Estercarbonyl Complex with Na Ions

Author(s) -

Seebach Dieter,

Müller HansMartin,

Bürger H. Michael,

Plattner Dietmar A.

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199204341

Subject(s) - polyhydroxybutyrate , chemistry , ion , sodium , metal , ring (chemistry) , polymer chemistry , inorganic chemistry , stereochemistry , organic chemistry , bacteria , genetics , biology

Ideally oriented to complex a metal ion , the three carbonyl groups of triolide 1 are parallel and pointing in the same direction. Upon complexation with a sodium ion, the ring adjusts by arching inward, tilting the CO groups towards each other. The preparation of triolide 1 from poly( R )‐3‐hydroxybutanoate is surprisingly simple.

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