Synthesis and Structure of the First Trinuclear, Half‐Sandwich Carboranegadolinium( III ) Cluster | Zendy

Oki Aderemi R. | Zendy; Zhang Hongming | Zendy; Hosmane Narayan S. | Zendy

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Synthesis and Structure of the First Trinuclear, Half‐Sandwich Carboranegadolinium( III ) Cluster

Author(s) -

Oki Aderemi R.,

Zhang Hongming,

Hosmane Narayan S.

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199204321

Subject(s) - prism , cluster (spacecraft) , crystallography , atom (system on chip) , spheres , symmetry (geometry) , triangular prism , ellipse , chemistry , plane (geometry) , molecular physics , geometry , materials science , physics , optics , mathematics , computer science , astronomy , embedded system , programming language

Six C 2 B 4 carborane cages surround the central region of cluster 1 , which has approximate C 3 symmetry. Six Li atoms make up a trigonal prism here viewed from the top; solid spheres represent atoms of the upper Li 3 plane, dotted spheres the (lower). Three Gd atoms (ellipses) cap the rectangular prism faces. In the center of the cluster is a μ‐bridged O atom.

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