Synthesis and Structure of [Ni(P t Bu 6 )] and [Ni 5 (P t Bu) 6 (CO) 5 ] and Calculations on the Electronic Structure of [Ni(P t Bu) 6 ] and (PR) 6 , R =  t Bu,Me | Zendy

Ahlrichs Reinhart | Zendy; Fenske Dieter | Zendy; Oesen Hannes | Zendy; Schneider Uwe | Zendy

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Synthesis and Structure of [Ni(P t Bu 6 )] and [Ni 5 (P t Bu) 6 (CO) 5 ] and Calculations on the Electronic Structure of [Ni(P t Bu) 6 ] and (PR) 6 , R = t Bu,Me

Author(s) -

Ahlrichs Reinhart,

Fenske Dieter,

Oesen Hannes,

Schneider Uwe

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199203231

Subject(s) - nickel , atom (system on chip) , center (category theory) , cluster (spacecraft) , crystallography , chemistry , planar , physics , computer science , parallel computing , computer graphics (images) , organic chemistry , programming language

A planar P 6 ‐ring, with a Ni atom located at its center , characterizes the novel complex, [Ni(P t Bu) 6 ] ( 1 ), shown here. This NiP 6 complex is formed upon reaction of (P t Bu) 3 with NiCl 2 and P(SiMe 3 ) 3 . In contrast, reaction of (P t Bu) 3 with [Ni(CO) 4 ] affords the pentanuclear cluster [Ni 5 (P t Bu) 3 (P 3 t Bu 3 )‐(CO) 5 ].

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