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Synthesis and Structure of [Ni(P t Bu 6 )] and [Ni 5 (P t Bu) 6 (CO) 5 ] and Calculations on the Electronic Structure of [Ni(P t Bu) 6 ] and (PR) 6 , R = t Bu,Me
Author(s) -
Ahlrichs Reinhart,
Fenske Dieter,
Oesen Hannes,
Schneider Uwe
Publication year - 1992
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199203231
Subject(s) - nickel , atom (system on chip) , center (category theory) , cluster (spacecraft) , crystallography , chemistry , planar , physics , computer science , parallel computing , computer graphics (images) , organic chemistry , programming language
A planar P 6 ‐ring, with a Ni atom located at its center , characterizes the novel complex, [Ni(P t Bu) 6 ] ( 1 ), shown here. This NiP 6 complex is formed upon reaction of (P t Bu) 3 with NiCl 2 and P(SiMe 3 ) 3 . In contrast, reaction of (P t Bu) 3 with [Ni(CO) 4 ] affords the pentanuclear cluster [Ni 5 (P t Bu) 3 (P 3 t Bu 3 )‐(CO) 5 ].