A Donor Cage with Two Tetrathiafulvene Units | Zendy

Adam Martin | Zendy; Enkelmann Volker | Zendy; Räder HansJoachim | Zendy; Röhrich Jörg | Zendy; Müllen Klaus | Zendy

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A Donor Cage with Two Tetrathiafulvene Units

Author(s) -

Adam Martin,

Enkelmann Volker,

Räder HansJoachim,

Röhrich Jörg,

Müllen Klaus

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199203091

Subject(s) - cage , hydroquinone , cyclophane , solid state , bent molecular geometry , monomer , chemistry , molecule , crystallography , tetra , stereochemistry , organic chemistry , medicinal chemistry , mathematics , combinatorics , polymer

Cyclophane 1 with four donor units (two tetra‐thiafulvalene (TTF) and two hydroquinone units) can be prepared by anodic oxidation of a strained cyclic “monomer” containing both of these donor components. Although in the solid state the TTF units in 1 are bent towards the cavity, making it too small for guest molecules, force‐field calculations show that in solution conformations with a sufficiently large cavity may arise. R = propyl, butyl.

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