Crystalline Nitrogen Oxides—Crystal Structure of N 2 O 3  and a Remark Concerning the Crystal Structure of N 2 O 5 | Zendy

Simon Arndt | Zendy; Horakh Jörg | Zendy; Obermeyer Axel | Zendy; Borrmann Horst | Zendy

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Crystalline Nitrogen Oxides—Crystal Structure of N 2 O 3 and a Remark Concerning the Crystal Structure of N 2 O 5

Author(s) -

Simon Arndt,

Horakh Jörg,

Obermeyer Axel,

Borrmann Horst

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199203011

Subject(s) - crystal structure , crystallography , molecule , unit (ring theory) , planar , crystal (programming language) , nitrite , nitrogen , bond length , chemistry , materials science , mathematics , organic chemistry , computer science , programming language , mathematics education , computer graphics (images) , nitrate

N 2 O 3 (1) may be described as “nitrosyl nitrite”. Structural investigations with the modified Guinier technique revealed a nearly planar molecule; the nitrite and nitrosyl groups are only slightly twisted (3.7°) about the NN bond. Indications that the structure of N 2 O 5 should be revised were also found. The picture shows the unit cell of 1 .

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