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(Isocyanide)ruthenate Analogues of Tetracarbonylferrate
Author(s) -
Corella Joseph A.,
Thompson Robert L.,
Cooper N. John
Publication year - 1992
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199200831
Subject(s) - electrophile , ruthenium , isocyanide , chemistry , naphthalene , potassium , medicinal chemistry , organic chemistry , catalysis
The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2 , which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph 3 SnCl by oxidative addition to give 3 ( trans isomers). But 2 also reacts analogous to [Fe(CO) 4 ] 2− , with Si‐ and C‐electrophiles. R = t Bu, 2,6‐Me 2 C 6 H 3 .
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