A Water‐Complexed Organolithium Compound: [LiCH(CN) 2  · H 2 O · TMEDA] ∞ | Zendy

Lambert Christoph | Zendy; von Ragué Schleyer Paul | Zendy; Pieper Ursula | Zendy; Stalke Dietmar | Zendy

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A Water‐Complexed Organolithium Compound: [LiCH(CN) 2 · H 2 O · TMEDA] ∞

Author(s) -

Lambert Christoph,

von Ragué Schleyer Paul,

Pieper Ursula,

Stalke Dietmar

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199200771

Subject(s) - tetramethylethylenediamine , denticity , hydrogen bond , ligand (biochemistry) , chemistry , amine gas treating , crystallography , inorganic chemistry , medicinal chemistry , molecule , crystal structure , organic chemistry , biochemistry , receptor

Not the bidentate amine ligand, but water coordinates to the Li cation in [LiCH(CN) 2 · H 2 O · TMEDA] ∞ 1 (TMEDA = tetramethylethylenediamine), a very unusual structural characteristic for lithiated organic compounds. Inter‐molecular hydrogen bonds between the H atoms of the aqua ligands and the N atoms of TMEDA are observed. 1 is therefore the first water‐complexed lithiated organic compound derived from a CH acid.

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