The Synthesis of the First Decametal Nitrido Cluster; X‐Ray Structure Analysis and  14 N NMR Studies of [(Ph 3 P) 2 N][Ru 10 N(CO) 24 ] | Zendy

Bailey Philip J. | Zendy; Conole Gráinne C. | Zendy; Johnson Brain F. G. | Zendy; Lewis Jack | Zendy; McPartlin Mary | Zendy; Moule Adrian | Zendy; Wilkinson Della A. | Zendy

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The Synthesis of the First Decametal Nitrido Cluster; X‐Ray Structure Analysis and 14 N NMR Studies of [(Ph 3 P) 2 N][Ru 10 N(CO) 24 ]

Author(s) -

Bailey Philip J.,

Conole Gráinne C.,

Johnson Brain F. G.,

Lewis Jack,

McPartlin Mary,

Moule Adrian,

Wilkinson Della A.

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199117061

Subject(s) - octahedron , cluster (spacecraft) , crystallography , chemistry , metal , impurity , stereochemistry , crystal structure , organic chemistry , computer science , programming language

A fourfold capped octahedral metal framework known previously only in carbido and hydrido clusters constitutes the structure of the monoanion [Ru 10 N(CO) 24 ] − (picture right). This cluster may be prepared in several ways; if forms without impurities that are difficult to remove on reaction of the octahedral cluster [Ru 6 N(CO) 16 ] − with [Ru 3 (CO) 12 ].

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