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The Synthesis of the First Decametal Nitrido Cluster; X‐Ray Structure Analysis and 14 N NMR Studies of [(Ph 3 P) 2 N][Ru 10 N(CO) 24 ]
Author(s) -
Bailey Philip J.,
Conole Gráinne C.,
Johnson Brain F. G.,
Lewis Jack,
McPartlin Mary,
Moule Adrian,
Wilkinson Della A.
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199117061
Subject(s) - octahedron , cluster (spacecraft) , crystallography , chemistry , metal , impurity , stereochemistry , crystal structure , organic chemistry , computer science , programming language
A fourfold capped octahedral metal framework known previously only in carbido and hydrido clusters constitutes the structure of the monoanion [Ru 10 N(CO) 24 ] − (picture right). This cluster may be prepared in several ways; if forms without impurities that are difficult to remove on reaction of the octahedral cluster [Ru 6 N(CO) 16 ] − with [Ru 3 (CO) 12 ].