New Routes to the Synthesis of Polymers Containing Nitrile Groups | Zendy

Brackemann Holger | Zendy; Buback Michael | Zendy; Rindfleisch Frank | Zendy; Rohde Stefan | Zendy

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New Routes to the Synthesis of Polymers Containing Nitrile Groups

Author(s) -

Brackemann Holger,

Buback Michael,

Rindfleisch Frank,

Rohde Stefan

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199116541

Subject(s) - copolymer , nitrile , acrylonitrile , polymer , elastomer , polymer chemistry , acrylate , materials science , excimer laser , functional polymers , polymer science , chemistry , organic chemistry , laser , composite material , physics , optics

Polymers consisting of pure CC chains and nitrile substituents promise to be competitive elastomers. This type of polymer can now be prepared by two routes : firstly by direct excimer laser‐induced free‐radical copolymerization of ethene and acrylonitrile and secondly by a polymer modification reaction of ethene‐acrylate copolymer in dense fluid ammonia [Eq. (a)].

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