The Reaction of PtCl 2  with an  N,S,O ‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion | Zendy

Davidson Matthew G. | Zendy; Raithby Paul R. | Zendy; Snaith Ronald | Zendy; Stalke Dietmar | Zendy; Wright Dominic S. | Zendy

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The Reaction of PtCl 2 with an N,S,O ‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion

Author(s) -

Davidson Matthew G.,

Raithby Paul R.,

Snaith Ronald,

Stalke Dietmar,

Wright Dominic S.

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199116481

Subject(s) - heteronuclear molecule , chemistry , adduct , salt (chemistry) , ion , toluene , calcium , medicinal chemistry , stereochemistry , inorganic chemistry , nuclear magnetic resonance spectroscopy , organic chemistry

A Ca 2 complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1 . It is obtained from a reaction of solid PtCl 2 with [Ox 2 Ca(HMPA) 2 ] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt 2+ with DNA bases.

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