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The Reaction of PtCl 2 with an N,S,O ‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion
Author(s) -
Davidson Matthew G.,
Raithby Paul R.,
Snaith Ronald,
Stalke Dietmar,
Wright Dominic S.
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199116481
Subject(s) - heteronuclear molecule , chemistry , adduct , salt (chemistry) , ion , toluene , calcium , medicinal chemistry , stereochemistry , inorganic chemistry , nuclear magnetic resonance spectroscopy , organic chemistry
A Ca 2 complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1 . It is obtained from a reaction of solid PtCl 2 with [Ox 2 Ca(HMPA) 2 ] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt 2+ with DNA bases.