Metal‐Assisted Organization rather than Preorganization for the Design of Macrocyclic Hosts | Zendy

Kobuke Yoshiaki | Zendy; Sumida Yasutaka | Zendy; Hayashi Minoru | Zendy; Ogoshi Hisanobu | Zendy

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Metal‐Assisted Organization rather than Preorganization for the Design of Macrocyclic Hosts

Author(s) -

Kobuke Yoshiaki,

Sumida Yasutaka,

Hayashi Minoru,

Ogoshi Hisanobu

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199114961

Subject(s) - alkali metal , boric acid , flexibility (engineering) , chemistry , metal , bicyclic molecule , combinatorial chemistry , stereochemistry , inorganic chemistry , nanotechnology , materials science , organic chemistry , mathematics , statistics

Boric acid initiates the formation of coronand 1 from 2 , providing the framework necessary for the strong complexation of alkali metal ions. This approach to the synthesis of the macrocyclic host allows a greater flexibility than the standard preorganization method. A bicyclic coronand is also obtained by this strategy. M = K, Na.

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