Premium
[FCNF] + [AsF 6 ] − , a Salt of the Linear 22‐Valence Electron Cation [FCNF] +
Author(s) -
TornieporthOetting Inis C.,
Gowik Petra,
Klapötke Thomas M.
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199114851
Subject(s) - ion , valence (chemistry) , chemistry , hydrogen fluoride , electron , ab initio quantum chemistry methods , hydrogen , atomic physics , valence electron , ab initio , spectral line , fluoride , analytical chemistry (journal) , inorganic chemistry , physics , molecule , nuclear physics , chromatography , astronomy , organic chemistry
Fluorination of the [HCNH] + ion of 1 in hydrogen fluoride produces the 30‐electron cation [FCNF] + of 2 . According to 19 F NMR and vibrational spectra this ion has a linear structure, which is in agreement with the predictions made by ab initio calculations.