Inclusion of Metal Ions within a Tin—Oxygen Cage Stabilized by Organic Residues: Crystal Structure of [( i PrSn) 12 O 4 (OH) 24 ][Ag 7 I 11 ] · NaCl · H 2 O · 10DMSO | Zendy

Reuter Hans | Zendy

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Inclusion of Metal Ions within a Tin—Oxygen Cage Stabilized by Organic Residues: Crystal Structure of [( i PrSn) 12 O 4 (OH) 24 ][Ag 7 I 11 ] · NaCl · H 2 O · 10DMSO

Author(s) -

Reuter Hans

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199114821

Subject(s) - crystallography , tin , ion , chemistry , oxygen atom , crystal structure , metal , isopropyl , oxygen , atom (system on chip) , inorganic chemistry , molecule , medicinal chemistry , organic chemistry , computer science , embedded system

Around a sodium atom template the spherically shaped shell of the dodecameric organotin–oxygen cation of the title compound assembles. (See polyhedral representation, right; the black dots symbolize isopropyl groups.) The [Ag 7 I 11 ] anion of this novel inorganic host–guest complex is also quite remarkable. It is a one‐dimensional, twisted double band of face‐sharing iodine tetrahedrons, leading one to expect a high silver‐ion conductivity.

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