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Inclusion of Metal Ions within a Tin—Oxygen Cage Stabilized by Organic Residues: Crystal Structure of [( i PrSn) 12 O 4 (OH) 24 ][Ag 7 I 11 ] · NaCl · H 2 O · 10DMSO
Author(s) -
Reuter Hans
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199114821
Subject(s) - crystallography , tin , ion , chemistry , oxygen atom , crystal structure , metal , isopropyl , oxygen , atom (system on chip) , inorganic chemistry , molecule , medicinal chemistry , organic chemistry , computer science , embedded system
Around a sodium atom template the spherically shaped shell of the dodecameric organotin–oxygen cation of the title compound assembles. (See polyhedral representation, right; the black dots symbolize isopropyl groups.) The [Ag 7 I 11 ] anion of this novel inorganic host–guest complex is also quite remarkable. It is a one‐dimensional, twisted double band of face‐sharing iodine tetrahedrons, leading one to expect a high silver‐ion conductivity.