Observation of a Direct SnLi Bond; The Crystal and Molecular Structure of Monomeric [Ph 3 SnLi · PMDETA] and the Detection of  119, 117 Sn 7 Li NMR Coupling in Solution | Zendy

Reed David | Zendy; Stalke Dietmar | Zendy; Wright Dominic S. | Zendy

Premium

Observation of a Direct SnLi Bond; The Crystal and Molecular Structure of Monomeric [Ph 3 SnLi · PMDETA] and the Detection of 119, 117 Sn 7 Li NMR Coupling in Solution

Author(s) -

Reed David,

Stalke Dietmar,

Wright Dominic S.

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199114591

Subject(s) - chemistry , monomer , crystallography , crystal structure , metalation , ligand (biochemistry) , amine gas treating , solid state , coupling (piping) , nuclear magnetic resonance spectroscopy , stereochemistry , materials science , polymer , organic chemistry , biochemistry , receptor , metallurgy

The metalation of Ph 3 SnH with n BuLi in the presence of the tridentate amine ligand N , N , N ′, N ″, N ″‐pentamethyldiethylenetriamine (PMDETA) provides the title compound. Crystal structure analysis shows this to be monomeric in the solid state and to contain a direct SnLi bond. This structure is preserved in solution, as demonstrated in low‐temperature 7 Li NMR studies.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research