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Azarhoda‐ closo ‐dodecaborane
Author(s) -
Hansen HansPeter,
Müller Jens,
Englert Ulrich,
Paetzold Peter
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199113771
Subject(s) - rhodium , chemistry , ion , crystallography , bridging (networking) , ligand (biochemistry) , atom (system on chip) , stereochemistry , catalysis , organic chemistry , biochemistry , receptor , computer science , embedded system , computer network
A distorted RhNB 10 icosahedron containing a six‐fold coordinated N atom forms the basic structure of the complex [{(Ph 3 P) 2 RhH}NB 10 H 11 ] ( 1 , depicted to the right without the PPh 3 substituents), which is accessible from the anion nido ‐NB 10 H 12 −and [(Ph 3 P) 3 RhCl]. The open pentagonal side of the anion becomes a pentahapto ligand and the bridging H atoms migrate to rhodium.