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The Interaction of Tri‐ tert ‐butylgallium with White Phosphorus: Isolation of an Unusual Gallium Phosphorus Cluster
Author(s) -
Power Michael B.,
Barron Andrew R.
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199113531
Subject(s) - white phosphorus , gallium , phosphorus , tetrahedron , cluster (spacecraft) , chemistry , lewis acids and bases , inorganic chemistry , crystallography , organic chemistry , catalysis , computer science , programming language
A Gap 4 tricycle of type [1.1.1.0] is found in the structure of Ga 2 P 4 t Bu 6 , which forms at room temperature already from elemental phosphorus (P 4 ) and the Lewis acid Ga t Bu 3 . This reaction, in which one side of the P 4 tetrahedron is opened, provides a surprisingly simple access to potential precursors for semiconductor materials of the III/IV type.
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