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Alkane Cascade Polymers Possessing Micellar Topology: Micellanoic Acid Derivatives
Author(s) -
Newkome George R.,
Moorefield Charles N.,
Baker Gregory R.,
Johnson Andrew L.,
Behera Rajani K.
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199111761
Subject(s) - alkene , cascade , heteroatom , branching (polymer chemistry) , polymer , alkane , chemistry , topology (electrical circuits) , organic chemistry , combinatorial chemistry , stereochemistry , materials science , hydrocarbon , alkyl , mathematics , catalysis , chromatography , combinatorics
The addition of a tertiary radical to an electron‐deficient alkene proves to be the decisve step in the synthesis of the four‐directional cascade polymers 1 and 2 , which have no heteroatoms in the initial core, in the branching centers, or in the repeat units. Only the periphery is highly fuctionalized.