Intramolecular Base Stabilization of SiN and SiP Compounds and Related Transition‐Metal Silanediyl Complexes | Zendy

Corriu Robert | Zendy; Lanneau Gérard | Zendy; Priou Christian | Zendy

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Intramolecular Base Stabilization of SiN and SiP Compounds and Related Transition‐Metal Silanediyl Complexes

Author(s) -

Corriu Robert,

Lanneau Gérard,

Priou Christian

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199111301

Subject(s) - intramolecular force , imine , silane , torr , acetone , chemistry , base (topology) , silicon , transition metal , metal , base metal , polymer chemistry , medicinal chemistry , stereochemistry , organic chemistry , materials science , catalysis , metallurgy , mathematics , mathematical analysis , physics , thermodynamics , welding

The high activity of low‐coordinated silicon compounds can be effectively reduced by intramolecular base stabilization: thus the silane imine 1 can be distilled at 175°C/2 × 10 −2 torr without dimerization, the silaphosphene 2 can be sublimed at 220°C/10 −2 torr, and the silanediyl complexes 3 and 4 can be recrystallized from acetone.

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