Rubyrin: A New Hexapyrrolic Expanded Porphyrin | Zendy

Sessler Jonathan L. | Zendy; Morishima Takashi | Zendy; Lynch Vincent | Zendy

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Rubyrin: A New Hexapyrrolic Expanded Porphyrin

Author(s) -

Sessler Jonathan L.,

Morishima Takashi,

Lynch Vincent

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199109771

Subject(s) - porphyrin , derivative (finance) , alkyl , chemistry , molecule , crystal (programming language) , photochemistry , stereochemistry , crystallography , organic chemistry , computer science , business , finance , programming language

The intense bright red color of the diprotonated derivatives of rubyrin ( 1 ), the largest expanded porphyrin to be characterized so far, is the source of the compound's name. A diprotonated alkyl derivative of 1 was synthesized efficiently. The molecule is nearly planar in the crystal—not unexpected for a large porphyrin‐like aromatic macrocycle.

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