The Structure of IF       8    ⊖ | Zendy

Mahjoub AliReza | Zendy; Seppelt Konrad | Zendy

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The Structure of IF 8 ⊖

Author(s) -

Mahjoub AliReza,

Seppelt Konrad

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199108761

Subject(s) - lone pair , square (algebra) , counterion , atom (system on chip) , crystallography , square pyramidal molecular geometry , chemistry , charge (physics) , atomic physics , physics , ion , crystal structure , molecule , mathematics , geometry , quantum mechanics , organic chemistry , computer science , embedded system

The square‐antiprismatic structure of IF 8 ⊖corresponds to that of XeF 8 2⊖ . This shows that the extra lone pair of XeF 8 2⊖is located in a stereochemically inactive orbital. The counterion NO ⊕ (NOF) 2 is a polymer in which the charge‐carrying N atom is surrounded by one O and four F atoms in a square‐pyramidal arrangement.

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