cyclo ‐As 8 , as Complex Ligand | Zendy

Scherer Otto J. | Zendy; Winter Rainer | Zendy; Heckmann Gert | Zendy; Wolmershäuser Gotthelf | Zendy

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cyclo ‐As 8 , as Complex Ligand

Author(s) -

Scherer Otto J.,

Winter Rainer,

Heckmann Gert,

Wolmershäuser Gotthelf

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199108501

Subject(s) - cyclooctatetraene , ligand (biochemistry) , ring (chemistry) , niobium , chemistry , crystallography , atom (system on chip) , cluster (spacecraft) , stereochemistry , arsenic , molecule , organic chemistry , biochemistry , computer science , receptor , programming language , embedded system

The arsenic analogue of cyclooctatetraene cyclo ‐As 8 can be stabilized as a strongly distorted, puckered eight‐membered ring in a complex of niobium ( 1 ; each Nb atom also bears a 1,3‐di‐ tert ‐butylcyclopentadienyl ligand). Complex 1 reacts with [Cr(CO) 5 (thf)] to form a trinuclear Nb 2 Cr cluster.

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