Premium
Sr 2 Li[Fe 2 N 3 ] and Ba 2 Li[Fe 2 N 3 ]: Nitridoferrate( II ) Isotypes with ∞ 1 [(FeN 3/2 ) 2 5⊖ ] Anions
Author(s) -
Höhn Peter,
Haag Sabine,
Milius Wolfgang,
Kniep Rüdiger
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199108311
Subject(s) - crystallography , ion , trigonal crystal system , chemistry , planar , diagram , stereochemistry , crystal structure , mathematics , computer science , organic chemistry , statistics , computer graphics (images)
A strong structural relationship exists between B 2 S 3 and the formally isoelectronic polymeric anion aggregates of the title compounds. These consist of Fe 2 N 2 rings linked to form chains through common exocyclic N atoms. Distorted trigonal‐planar coordination is observed for the Fe II centers.(In the diagram, ○ represents N and • represents Fe.)