In 7 Cl 9 —A New “Old” Compound in the System In‐Cl | Zendy

Beck Horst Philipp | Zendy; Wilhelm Doris | Zendy

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In 7 Cl 9 —A New “Old” Compound in the System In‐Cl

Author(s) -

Beck Horst Philipp,

Wilhelm Doris

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199108241

Subject(s) - phase (matter) , crystallography , sintering , chemistry , stereochemistry , materials science , organic chemistry

Neither In 3 Cl 4 nor In 4 Cl 5 accurately defines a phase whose existence was predicted by thermoanalytic methods. In fact a more apt formula is In 7 Cl 9 , for the phase which is prepared from InCl/InCl 3 mixtures by sintering for 14 days at 220–250°C. The structure of the compound (part of which is shown on the right—In: small circles; Cl: large circles) reveals interesting crystallographic relationships to that of α‐InCl and is important in the discussion on stereochemical activity of cations with ns 2 configuration.

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