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Facile NH Cleavage of Ammonia
Author(s) -
Koelliker Robert,
Milstein David
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199107071
Subject(s) - cleavage (geology) , catalysis , ammonia , olefin fiber , chemistry , surface modification , medicinal chemistry , combinatorial chemistry , organic chemistry , materials science , fracture (geology) , composite material
The dinuclear Ir complex 1 already reacts with excess NH 3 at − 50°C to give not only mono– and dicationic complexes but also 2 , the first amido‐olefin complex. An NH activation under such exceptionally mild conditions is of interest for the catalytic functionalization of olefins with NH 3 .
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