Premium
Synthesis and Structure of the Novel Ga 3 P 3 Ring Compound [(2,4,6‐Ph 3 C 6 H 2 )GaP( cyclo ‐C 6 H 11 )] 3
Author(s) -
Hope Håkon,
Pestana Doris C.,
Power Philip P.
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199106911
Subject(s) - ring (chemistry) , citation , contrast (vision) , combinatorics , computer science , planar , information retrieval , mathematics , world wide web , computer graphics (images) , chemistry , artificial intelligence , organic chemistry
The central ring system in 1 consists exclusively of three‐coordinate heavy main group elements. In contrast to its BP analogue the Ga 3 P 3 ring is not planar, i.e. π‐π overlap with tem is not favored. Nevertheless, it contains the hitherto shortest GaP bond (mean length 2.3 Å).