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Metalla‐enes and Metalla‐ynes—from Small Molecules to Infinite Polymers
Author(s) -
Chisholm Malcolm H.
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199106731
Subject(s) - polymer , conjugated system , materials science , polymer chemistry , molecule , nonlinear optical , lewis acids and bases , metal , polymer science , chemistry , nonlinear system , physics , organic chemistry , catalysis , composite material , metallurgy , quantum mechanics
Inorganic polymers with conjugated multiple bonds and metal atoms in the polymer main chain have recently been the subject of a series of publications. Such materials are of interest, inter alia, because of anticipated nonlinear optical properties. Marder et al. and Lewis et al. have synthesized polymeric alkynerhodium complexes such as 1 , while Hopkins et al. have studied the optical properties of the polymeric nitrido complexes 2 .