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A Stable Os 0 16‐Electron Complex: Synthesis and Structure of [OsCI(NO)(P i Pr 3 ) 2 ]
Author(s) -
Werner Helmut,
Michenfelder Annette,
Schulz Michael
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199105961
Subject(s) - osmium , reactivity (psychology) , denticity , chemistry , ligand (biochemistry) , block (permutation group theory) , stereochemistry , crystallography , crystal structure , ruthenium , combinatorics , mathematics , organic chemistry , catalysis , medicine , biochemistry , alternative medicine , receptor , pathology
An osmium(0) complex of the type [OsL 4 ] (L = monodentate ligand), namely, [OsCl(NO)(P i Pr 3 ) 2 ] ( l ), was synthesized. Its reactivity toward Lewis acids and bases makes 1 a valuable building block in the synthesis of Os o and Os II complexes.