A 1,2‐Phenylene‐Bridged Porphyrin Dimer—Synthesis, Properties, and Molecular Structure | Zendy

Osuka Atsuhiro | Zendy; Nakajima Satoshi | Zendy; Nagata Toshi | Zendy; Maruyama Kazuhiro | Zendy; Toriumi Koshiro | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A 1,2‐Phenylene‐Bridged Porphyrin Dimer—Synthesis, Properties, and Molecular Structure

Author(s) -

Osuka Atsuhiro,

Nakajima Satoshi,

Nagata Toshi,

Maruyama Kazuhiro,

Toriumi Koshiro

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199105821

Subject(s) - porphyrin , dimer , phenylene , photochemistry , planar , chemistry , crystallography , electron transport chain , photosynthetic reaction centre , materials science , electron transfer , organic chemistry , computer science , polymer , biochemistry , computer graphics (images)

The porphyrin rings in the porphyrin dimer 1 are nearly planar, but they are considerably tilted toward each other. Compound 1 is of interest as a model for the special pair of the photosynthetic reaction center. The average distance between the two porphyrin planes is only 3.43 Å. The resulting strong interactions—resembling those in excimers—lead to a lowering of the energy of the S 1 state and facilitate one‐electron oxidation.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research