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Carbonyl(pentaphosphacyclopentadienyl)‐Transition Metal Complexes (M Cr, Mo, W, Mn) through Directed Syntheses with cyclo‐P 5 ⊖
Author(s) -
Baudler Marianne,
Etzbach Thomas
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199105801
Subject(s) - transition metal , chemistry , metal carbonyl , thermal stability , ligand (biochemistry) , metal , manganese , ion exchange , inorganic chemistry , polymer chemistry , ion , organic chemistry , catalysis , receptor , biochemistry
Simple thermal ligand exchange allows the carbonyl( pentaphosphacyclopentadienyl) complexes 1 (n = 1, M = Cr, Mo, W; n = 0, M = Mn) to be prepared. These reactions demonstrate the stability of the free P 5 ⊖ion.
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