Difference Electron Densities in a Spiropentene | Zendy

Irngartinger Hermann | Zendy; Gries Stefan | Zendy

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Difference Electron Densities in a Spiropentene

Author(s) -

Irngartinger Hermann,

Gries Stefan

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199105651

Subject(s) - bent molecular geometry , electron density , crystallography , electron , diffraction , bond length , bending , bent bond , double bond , electron diffraction , molecular geometry , bond , materials science , chemistry , molecular physics , atomic physics , bond order , physics , optics , molecule , crystal structure , composite material , nuclear physics , organic chemistry , finance , polymer chemistry , economics

The strong bending of the bonds in the spiropentene 1 was confirmed by low‐temperature X‐ray diffraction measurements (105 K) using the X‐X method. The double bond in 1 is one of the most bent olefinic bonds known; the angle between the bond axis and the lines drawn from the C atoms to the electron density maximum is 15 o .

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