Benzene Bis(diazocyanides)—the First Acceptors of the Inverse Wurster Type for Conductive Organic Materials | Zendy

Almen Hartmut | Zendy; Bauer Thomas | Zendy; Hünig Siegfried | Zendy; Kupčik Vladimir | Zendy; Langohr Uwe | Zendy; Metzenthin Tobias | Zendy; Meyer Klaus | Zendy; Rieder Harald | Zendy; von Schütz Jost Ulrich | Zendy; Tillmanns Ekkehart | Zendy; Wolf Hans Christoph | Zendy

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Benzene Bis(diazocyanides)—the First Acceptors of the Inverse Wurster Type for Conductive Organic Materials

Author(s) -

Almen Hartmut,

Bauer Thomas,

Hünig Siegfried,

Kupčik Vladimir,

Langohr Uwe,

Metzenthin Tobias,

Meyer Klaus,

Rieder Harald,

von Schütz Jost Ulrich,

Tillmanns Ekkehart,

Wolf Hans Christoph

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199105611

Subject(s) - tetrathiafulvalene , tetracyanoquinodimethane , character (mathematics) , benzene , homo/lumo , chemistry , redox , ion , inverse , polymer chemistry , photochemistry , materials science , organic chemistry , molecule , geometry , mathematics

The potentials and LUMO energies of the new two‐stage redox systems 1 of inverse Wurster type are similar to those of TCNQ and DCNQI. In contrast to TCNQ, however, these systems have an oxidized form with aromatic character and a reduced form with quinonoid character. Despite a different orbital symmetry, compounds 1 act as acceptors in conducting CT complexes (with tetrathiafulvalene, for example) and in radical ion salts.

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