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Bicyclic P 6 as Complex Ligand
Author(s) -
Scherer Otto J.,
Werner Bernd,
Heckmann Gert,
Wolmershäuser Gotthelf
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199105531
Subject(s) - bicyclic molecule , ligand (biochemistry) , toluene , chemistry , colored , stereochemistry , materials science , organic chemistry , biochemistry , composite material , receptor
The binuclear Th complex 1 contains a new type of P 6 ligand , which is derived formally from P 6 benzvalene. Amber‐colored, extremely air‐sensitive crystals of 1 are formed on cothermolysis of the butadiene complex [Cp 2 Th(η 4 ‐C 4 H 6 ] and P 4 in toluene.
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