[{Re 2 Cl 4 (dppm) 2 } 2  (μ‐TCNQ)], a Novel Charge Transfer Complex Derived from a Donor with a Metal‐Metal Multiple Bond | Zendy

Bartley Stuart L. | Zendy; Dunbar Kim R. | Zendy

Premium

[{Re 2 Cl 4 (dppm) 2 } 2 (μ‐TCNQ)], a Novel Charge Transfer Complex Derived from a Donor with a Metal‐Metal Multiple Bond

Author(s) -

Bartley Stuart L.,

Dunbar Kim R.

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199104481

Subject(s) - metal , tetracyanoquinodimethane , charge (physics) , crystallography , chemistry , transfer (computing) , charge transfer complex , conductivity , materials science , molecule , physics , photochemistry , organic chemistry , quantum mechanics , parallel computing , computer science

Black crystals of the title complex are obtained by slow diffusion of THF solutions of [Re 2 Cl 4 , (dppm) 2 ] (ReRe) and tetracyanoquinodimethane (TCNQ). Although their conductivity is only ca. 10 −5 S cm −1 , the magnetic and structural features of this charge transfer complex are remarkable. The bridging of two metal complexes by a TCNQ unit is without precedent. The concept of using metal‐metal multiple‐bond systems as donors for inorganic/organic CT complexes appears viable.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research