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The Neutral Transition Metal Thiolates [M(SAr) 2 ] 2 (M Mn, Fe or Co, Ar 2,4,6‐ t ‐Bu 3 C 6 H 2 )
Author(s) -
Power Philip P.,
Shoner Steven C.
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199103301
Subject(s) - transition metal , planar , crystallography , metal , molecule , chemistry , unit (ring theory) , trigonal crystal system , materials science , crystal structure , computer science , mathematics , computer graphics (images) , organic chemistry , catalysis , biochemistry , mathematics education
Not a polymeric structure, but discrete molecules are present in the thiolate complexes [{M(SAr) 2 } 2 ] (M Mn, Fe ( 1 ). Co; Ar 2,4,6‐ t Bu 3 C 6 H 2 ). The central [M 2 S 2 ] unit is planar, the metal atoms are surrounded in an almost trigonal planar fashion. Thiolato transition‐metal complexes are relevant as models for investigating the active centers in metalloproteins.