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RS‐PS in the Gas Phase—First Generation of (Organothio)thioxophosphanes
Author(s) -
Keck Helmut,
Kuchen Wilhelm,
Renneberg Heike,
Terlouw Johan K.,
Visser Herman C.
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199103181
Subject(s) - reionization , gas phase , atom (system on chip) , ionization , mass spectrometry , chemistry , phase (matter) , collision , spectroscopy , electron , electron ionization , atomic physics , ion , physics , organic chemistry , nuclear physics , computer science , chromatography , quantum mechanics , embedded system , computer security
A two‐coordinate, trivalent phosphorus atom is present in the title compounds 1 (R CH 3 , C 6 H 5 ), which are formed by electron collision ionization of the corresponding dithiadiphosphetane disulfides 2 . Collision activation and neutralization‐reionization mass spectroscopy show that the isomeric dithioxophosphoranes 3 rearrange to 1 .