RS‐PS in the Gas Phase—First Generation of (Organothio)thioxophosphanes | Zendy

Keck Helmut | Zendy; Kuchen Wilhelm | Zendy; Renneberg Heike | Zendy; Terlouw Johan K. | Zendy; Visser Herman C. | Zendy

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RS‐PS in the Gas Phase—First Generation of (Organothio)thioxophosphanes

Author(s) -

Keck Helmut,

Kuchen Wilhelm,

Renneberg Heike,

Terlouw Johan K.,

Visser Herman C.

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199103181

Subject(s) - reionization , gas phase , atom (system on chip) , ionization , mass spectrometry , chemistry , phase (matter) , collision , spectroscopy , electron , electron ionization , atomic physics , ion , physics , organic chemistry , nuclear physics , computer science , chromatography , quantum mechanics , embedded system , computer security

A two‐coordinate, trivalent phosphorus atom is present in the title compounds 1 (R CH 3 , C 6 H 5 ), which are formed by electron collision ionization of the corresponding dithiadiphosphetane disulfides 2 . Collision activation and neutralization‐reionization mass spectroscopy show that the isomeric dithioxophosphoranes 3 rearrange to 1 .

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