Cooligomerization of Phosphaalkynes and Alkynes in the Coordination Sphere of Rhodium Complexes | Zendy

Binger Paul | Zendy; Haas Josef | Zendy; Herrmann Albert T. | Zendy; Langhauser Franz | Zendy; Krüger Carl | Zendy

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Cooligomerization of Phosphaalkynes and Alkynes in the Coordination Sphere of Rhodium Complexes

Author(s) -

Binger Paul,

Haas Josef,

Herrmann Albert T.,

Langhauser Franz,

Krüger Carl

Publication year - 1991

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199103101

Subject(s) - chemistry , coordination sphere , bipyramid , ligand (biochemistry) , tetragonal crystal system , rhodium , trigonal bipyramidal molecular geometry , crystallography , crystal structure , pentagonal bipyramidal molecular geometry , stereochemistry , catalysis , organic chemistry , biochemistry , receptor

The 1‐phospha‐2‐rhodacyclobutene 2 is formed upon reaction of the vinylidene complex 1 with tert ‐butylphosphaacetylene and subsequent ligand substitution. In the crystal, 2 can be described as a slightly distorted tetragonal bipyramid with a free coordination site.

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